| Sl# | SAMS Code | CHSE Code | District Name | Block Name | College Name |
| 1 | 27012101 | HD04 | Rayagada | Bissamcuttack | Maa Markama Higher Secondary School, Bisam Cuttack |
| 2 | 27026101 | HD34 | Rayagada | Chandrapur | Government (SSD) Girls Higher Secondary School, Chandrapur |
| 3 | 27032101 | HD08 | Rayagada | Gudari | Science Higher Secondary School, Gudari |
| 4 | 27042101 | HD02 | Rayagada | Gunupur | Gunupur Higher Secondary School, Gunupur |
| 5 | 27045101 | HD21 | Rayagada | Gunupur | Maharshi Gurukul Science Higher Secondary School, Gunupur |
| 6 | 27045102 | HD28 | Rayagada | Gunupur | Shantiniketan Higher Secondary School, Gunupur |
| 7 | 27045104 | HD30 | Rayagada | Gunupur | Gayatri Higher Secondary School of Science, Gyana Vihar, Gunupur |
| 8 | 27048101 | HD14 | Rayagada | Gunupur | Dr. B.R.N. Higher Secondary School, Dombosora |
| 9 | 27048202 | HD10 | Rayagada | Gunupur | Thyarama Women's Higher Secondary School, Gunupur |
| 10 | 27103101 | HD24 | Rayagada | K.Singpur | Devagiri Higher Secondary School,Kalyansinghpur |
| 11 | 27106101 | HD23 | Rayagada | K.Singpur | Government (SSD) Higher Secondary School, Siripur |
| 12 | 27118101 | HD11 | Rayagada | Kasipur | Manikeswari Adivasi Higher Secondary School, Kashipur |
| 13 | 27116102 | HD25 | Rayagada | Kasipur | Government Higher Secondary School, Dongasil |
| 14 | 27125101 | HD29 | Rayagada | Kolnara | Kabi Balaram Sakuntala Higher Secondary School, Gunakhal, Therubali |
| 15 | 27126101 | HD16 | Rayagada | Kolnara | Government (SSD) Higher Secondary School, Kailashpur |
| 16 | 27055101 | HD20 | Rayagada | Muniguda | Royal Science Higher Secondary School, Muniguda |
| 17 | 27055107 | HD31 | Rayagada | Muniguda | Rising Higher Secondary School, Muniguda |
| 18 | 27058101 | HD13 | Rayagada | Muniguda | Ambodala Samant Higher Secondary School, Ambadola |
| 19 | 27052101 | HD05 | Rayagada | Muniguda | Muniguda Higher Secondary School, Gobardhana |
| 20 | 27056101 | HD22 | Rayagada | Muniguda | Government (SSD) Higher Secondary School, Ambodala |
| 21 | 27065102 | HD27 | Rayagada | Padampur | Triveni Science Higher Secondary School, Padmapur |
| 22 | 27068101 | HD06 | Rayagada | Padampur | R.G. Higher Secondary School, Padmapur |
| 23 | 27075101 | - | Rayagada | Ramanaguda | Adibasi Kalyan Parishad Higher Secondary School, Badisola |
| 24 | 27072101 | HD01 | Rayagada | Ramanaguda | Droupadi Higher Secondary School, Gumuda |
| 25 | 27135101 | HD19 | Rayagada | Rayagada | JITM Science Residential Higher Secondary School, Rayagada |
| 26 | 27132101 | HD03 | Rayagada | Rayagada | Lakshmipati Singania Higher Secondary School, Jaykaypur |
| 27 | 27138101 | HD12 | Rayagada | Rayagada | Ugratara Higher Secondary School, Komtalpeta |
| 28 | 27135102 | HD32 | Rayagada | Rayagada | Jupiter Science Higher Secondary School, Rayagada |
| 29 | 27136101 | HD17 | Rayagada | Rayagada | Eklavya Model Residential Higher Secondary School, Siriguda |
| 30 | 27095101 | HD33 | Rayagada | Gunupur (NAC) | Bansadhara Higher Secondary School Gunupur |
| 31 | 27142101 | HD07 | Rayagada | Rayagada (MPL) | Rayagada Higher Secondary School, Rayagada |
| 32 | 27145101 | HD15 | Rayagada | Rayagada (MPL) | Sri Bharati Higher Secondary School, Devodal |
| 33 | 27142202 | HD09 | Rayagada | Rayagada (MPL) | Rayagada Women's Higher Secondary School, Rayagada |